The pressure-induced Mott insulator-to-metal transitions are often accompanied by a collapse of magnetic interactions associated with delocalization of 3d electrons and high-spin to low-spin (HS-LS) state transition. They indicate that the application of Fe 0.79 Si 0.07 B 0.14 metallic glass gaskets in XRD experiments for both axial and radial geometries substantially improves various aspects of megabar experiments and, in particular, the signal-to-noise ratio in comparison to that with conventional gaskets made of Re, W, steel or other crystalline metals. Our results emphasize the material's importance for a great number of delicate experiments conducted under extreme conditions. Ne, H 2 ) used as pressure-transmitting media or in those with laser heating in a DAC. We report that Fe 0.79 Si 0.07 B 0.14 metallic glass gaskets offer a stable sample environment under compression exceeding 1 Mbar in all XRD experiments described here, even in those involving small-molecule gases ( e.g. The experiments were conducted in either axial or radial geometry with X-ray beams of micrometre to sub-micrometre size. In this work, we studied the performance of gaskets made of metallic glass Fe 0.79 Si 0.07 B 0.14 in a number of high-pressure X-ray diffraction (XRD) experiments in DACs equipped with conventional and toroidal-shape diamond anvils. A gasket is an important constituent of a diamond anvil cell (DAC) assembly, responsible for the sample chamber stability at extreme conditions for X-ray diffraction studies.
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